The development of piezoelectric ceramics with high energy conversion efficiency is of decisive importance for the requirements of the advanced energy harvesting devices toward miniaturization and integration. Lead titanate-zirconate (PZT) piezoceramics are the most widely used energy harvesting (EH) materials due to their excellent …
Phase structure and properties of sodium bismuth titanate lead-free piezoelectric ceramics - ScienceDirect. Progress in Materials Science. Volume 122, …
The intensification of research on bismuth-containing borate systems has stimulated the development of an entire series of new glass compositions distinguished by high fusibility, special electric properties, high region of transmission, and nonlinear-optical properties. ... such as thermal and mechanical sensors, glass ceramics, reflecting ...
Among all kinds of lead-free piezoelectric ceramics, bismuth ferrite (BiFeO 3, BFO)-based ceramic with large strain response has been proved to be a promising candidate for actuator devices [3]. However, the device operation depends on ferroelectric polarization switching, and therefore, the reliability and long-term stability during …
Dielectric, ferroelectric, and piezoelectric properties including phase transition temperatures of perovskite-type bismuth sodium titanate, (Bi1/2Na1/2)TiO3 [BNT]-based lead-free piezoelectric ceramics have been reviewed from the results obtained by our group being superior candidates for lead-free piezoelectric materials to reduce environmental …
Bismuth layer structured lead free piezoelectric ceramics in the system Sr1−x Ca x Na0.5Bi4.5Ti5O18 + 1 wt% CeO2 (SC x NBTC; x = 0, 0.25, 0.5, 0.75 and 1) have been prepared through the conventional solid-state reaction method. X-ray diffraction measurement indicates that a single phase layered perovskite was obtained for all …
Origin of Polarization in Bismuth Sodium Titanate-Based Ceramics. Hangfeng Zhang., Marcin Krynski., A. Dominic Fortes., Theo Graves Saunders., …
Due to their good mechanical properties and stable piezoelectric properties, piezoelectric ceramics are multifunctional materials with a broad range of applications in multiple technological fields such as sensors, ultrasonic transducers, micro displacement devices, and other electronic components [1,2,3].PZT-based ferroelectric materials are …
Lustre glazes can be quite unpredictable so I take notes during every firing to learn from my mistakes and recreate successful results. BASE GLAZE RECIPE. Calcium borate frit 60g. Nepheline …
Bismuth titanate and lanthanum-doped bismuth titanate ceramics were prepared from freeze-dried powders employing conventional solid state reaction and sintering procedures. The sintering process was carried out at 1150 °C from 4 up to 48 h. X-ray diffraction analysis showed that preferred orientation was reduced in bismuth …
An open-circuit voltage of 6.9 V was received on oriented ceramic bismuth ferrite (BFO) thin-film solar cells working in an "out-of-plane" mode. The above-band-gap voltage is strongly related to the crystallinity, orientation, and thickness of the BFO film contributing to the bulk photovoltaic effects, which have been further verified by powder X …
Bismuth layer structured ferroelectrics (BLSFs) ceramics can be used to manufacture piezoelectric devices under high temperature due to their high Curie temperature [1–3]. So the BLSFs have been given more attentions in recent years [4–11]. Many studies concerning improving the Curie temperature of BLSFs ceramics for high temperature
The classical view of the structural changes that occur at the ferroelectric transition in perovskite-structured systems, such as BaTiO3, is that polarization occurs due to the off-center displacement of the B-site cations. Here, we show that in the bismuth sodium titanate (BNT)-based composition 0.2(Ba0.4Sr0.6TiO3)–0.8(Bi0.5Na0.5TiO3), this model …
July 2017 Nonstoichiometric Effects in the Leakage Current and Electrical Properties of Bismuth Ferrite Ceramics 325 (1) Here, R is the resistance [Ω], A is the specimen cross-section.
In this work, novel bismuth ferrite-based lead-free ceramics of (1-x)(0.67BiFeO 3-0.33BaTiO 3)-xNa 0.73 Bi 0.09 NbO 3 ((1-x)BFBT-xNBN) were designed and fabricated successfully by optimizing the polarization and electric field. With increasing the content of NBN, the remnant polarization decreased rapidly as well as the slim and …
In recent years the microwave sintering has been utilized for the synthesis of materials in enhancement of the properties. In this paper strontium bismuth niobate (Sr 0.8 Bi 2.2 Nb 2 O 9:SBN) bulk ceramic has been synthesized by microwave reactive sintering and conventional heating techniques.A relative density of 99.6% has been achieved for …
Here we observed a large strain of lead-free BiFeO 3 ternary ceramics by the composition design [(0.70-x)Bi 1.05 FeO 3-0.30BaTiO 3-xBi(Mg 2/3 Nb 1/3)O 3].Positive temperature dependence of strain under E = 4 kV/mm can be observed in the ceramics with x = 0.07.Large strain property (S = 0.32% and d 33 * = 800 pm/V) and low …
Among the different types of multiferroic compounds, bismuth ferrite (BiFeO3; BFO) stands out because it is perhaps the only one being simultaneously …
Sodium bismuth titanate-barium titanate (NBBT) piezoelectric ceramics have the characteristics of relaxed ferroelectrics. It is considered as the most promising lead …
The microscopic origin of the grain size effects on the dielectric, piezoelectric, and thermal depoling properties of Aurivillius phase Bi 3.15 Nd 0.85 Ti 3 O 12 was investigated. Using atomic force microscopy, domain walls were observed in micrometer grain size ceramics, but gradually disappeared with reducing grain size and were not …
New codoped composite bismuth layered compound (CaBi)1-x(LiMn)xBi6NbTi5O24 ceramics were obtained in a wide sintering temperature range. • The highest d33 was achieved at a low sintering temperature of 960 oC despite the moderate density.. The piezoelectricity (d33) was increased about 2 or 3 times of that of the end …
New lithium bismuth phosphate ceramic: crystal structure, microstructure, microwave dielectric properties and co-firing compatibility with aluminum electrode. …
Bismuth doped Sr 2 Fe 1.5 Mo 0.5 O 6-δ double perovskite as a robust fuel electrode in ceramic oxide cells for direct CO 2 electrolysis. Author links open overlay panel Meiting Yang a 1, Zhen Yao b 1, Shuai Liu a, Jun Wang a, Anwei Sun c, Haoran Xu c, Guangming Yang a, Ran Ran a, Wei Zhou a, Gang Xiao c, Zongping Shao a d.
Ca0.4Sr0.6Bi4Ti4O15 ceramics with a-axis preferred orientation were prepared by a solid-state reaction method. The cylindrical Ca(0.4)Sr(0.6)Bi(4)Ti(4)O(15)ceramics were cut into two types of ...
Bismuth sodium titanate (BNT) (Bi 0.5 Na 0.5 TiO 3) emerges as a prospective lead-free piezoelectric ceramic with improved characteristics, boasting a high residual polarization (P r) of 38 μC/cm 2 and coercive fields (E c) of 73 kV/cm [[7], [8], [9]]. The challenges associated with high coercive field, conductivity, and domain switching ...
The concept of high-entropy lead-free piezoelectric ceramics in this study provides a promising strategy for the exploration and development of the next generation of lead …
A new type of lithium bismuth phosphate 3Li2O–Bi2O3–6P2O5 (3L1B6P) microwave dielectric ceramics were prepared via a conventional solid-state route. Crystal structure, microstructure, microwave dielectric properties and aluminum electrode co-firing compatibility of the 3L1B6P ceramics were investigated. The 3L1B6P ceramics mainly …
Bismuth layer‐structured ferroelectrics with non‐sheet‐like polyhedral microstructures - He - 2021 - Journal of the American Ceramic Society - Wiley Online …
Fig. 3 shows the SEM images of BSF15 and BSF18 ceramics as representative example, while the images of the other compositions are given in the Supporting information as Fig. S6. The Bi 25 FeO 40 phase is mainly present at the grain boundaries, while Bi 2 Fe 4 O 9 is evidenced within the grains, in agreement with …
To understand the mechanism for this discrepancy, the flexoelectric response of the Na 0.5 Bi 0.5 TiO 3 –BaTiO 3 (NBBT) ceramics of different compositions was systematically studied. We show that the measured flexoelectric response of the NBBT ceramics is mainly from the piezoelectric response of the spontaneously polarized …
However, the effect of liquid phase on particle transport has not been explained definitely. Moreover, flash sintering has a prominent contribution in the preparation ceramics with highly volatile species, such as KNbO 3 [ 24 ], NaNbO 3 [ 25] and BiFeO 3 [ 26 ]. Sodium bismuth titanate (Na 0.5 Bi 0.5 )TiO 3 (NBT) is the best-known electronic ...